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HC12a/134+® vs. R134

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Technical Information on HC12a/134+®/HC22a/502a®

Introducing the All New
Meet the Refrigerants of Tomorrow
Refrigerant Overview
Thermodynamic Properties
Toxicity
Flammability
Environmental Effect
Compatability
Contamination
Handling and Detection
Abundance and Ease of Manufacturing

Why Do Compressors Fail?

Composition of Refrigerant Blends


Technical Information on HC12a/134+®/HC22a/502a®

HC12a/134+® and HC22a/502a® are patented hydrocarbon blends that were developed as effective replacements for non-ozone-depleting substitutes for CFC-12 (R-12), HFC-22 (R-22), and R502. HC12a/134+® is a superior replacement for R134a. The below information is a layman's overview of how these products rate in the critical measurements of the "ideal refrigerant".
Introducing the All New
HC12a/134+ and HC22a/502a

HC12a/134+ has remained the same blend, being the most efficient, safest, and most environmentally friendly refrigerant on the market today.

HC22a/502a has been enhanced to do a better job of replacing 502a while remaining the top replacement for 22a. The head pressure remains much lower with HC22a/502a than with either 502a or 22a.

HC12a/134+ and HC22a/502a have been packaged in less expensive cylinders (30# disposable cylinders) giving the installer a much lighter cylinder to handle and a much better price when buying.

Not only the best refrigerant in the world, now it is the best-priced refrigerant in the world. The new packaging is geared more toward the professional air condition technician. Everyone dealing with refrigerants should have (1) a set of gauges, (2) a recovery machine, and (3) a vacuum pump. These three items are very essential in doing the right kind of repairs to any air condition or refrigeration system. Without gauges who knows what the high side pressure is. Many compressor and ruptured hose jobs are done because too much refrigerant was put in without knowing the high pressure readings. A small, inexpensive job turned into a disaster when a set of gauges would have been much cheaper. How can we capture all of these destructive refrigerants without a recovery machine and tank? We should be studying these ozone depleting, earth warming, highly toxic chemicals we are dumping into the atmosphere. The United States has become the largest dumping ground in the world for bad refrigerants. The use of small cans seems to be the number one culprit.

We should all work together and try to clean up the mess we have made. A recent petition was sent to the USEPA showing over 1 million gallons of hydrocarbon refrigerants being used in the U.S. without 1 claim for injury being filed. This petition was supported by documents from four insurance companies, showing after ten years of use and 3 to 5 million cars being charged with hydrocarbons, not one single claim has been filed against these products. These insurance companies carry product liability on this refrigerant, and would be the first to know if a problem ever came up. The truth is sure different from propaganda and lies we all hear but cannot be documented. ALWAYS SEEK THE TRUTH.

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Meet the Refrigerants of Tomorrow
HC12a/134+ and HC22a/502a

These two amazing refrigerants will cover about 95% of all your air conditioning and refrigeration needs. These two refrigerants will blend with all refrigerant oils, mineral and synthetic. Choose the finest oil for the unit you are servicing and these refrigerants will blend with that oil and keep returning it back to your compressor. NOT ALL OILS THAT ARE RECOMMENDED ARE GOOD FOR THE UNITS. You need to study your oils. You can now eliminate all your Easter egg colored tanks and rely on the blue or green labels as to what tank you hook up to. You don't have to match oil to refrigerant anymore.

HC12a/134+ replaces HC22a/502a replaces
MP-39401aHP-80402a
MP-66401bHP-81402b
MP-52401cHP-62, FX-70404a
GHG406aKLEA 407a407a
FX-56-409aKLEA 407b407b
FR-12FX-10408a
GHG-HPR411a411a
Hot Shot414bR411b411b
GHG-X4414aG2018c
GHG-X5AZ-50507
Free ZoneKLEA407c
Freeze 12AC9000407c

One replacement for R22a being pushed is Puron 410. Remember when installing one of these systems, there is no replacement for this high-pressured refrigerant; it is considered a short term fill in for R22. With the high pressures 410 runs troubles are sure to happen. Later when things do go wrong the entire system will have to be replaced for lack of replacement refrigerants!!! This is called "keeping the economy turning"!!! At whose expense?

Nearly all of the above replaceable, synthetic refrigerants are either ozone depleting or earth warming blends. None are considered earth friendly. Foreign nations are already fazing these refrigerants out, soon to be followed by the United States. We have already seen the faze out of the worst ozone depleting refrigerants, now we're beginning to see the end of the earth warming refrigerants. In 2002, the Department of Energy passed regulations which require minimum efficiency from 10 SEER to 12 SEER on most residential units which goes into effect after 2005. To reach this goal you simply match a 4-ton air handler to a 3 1/2 ton condensing unit and charge with HC22a/502a, which will bring it to a 15 to 16 SEER unit.

Remember it takes less than half the weight when replacing original refrigerants with HC's. When charged properly a large drop in head pressure should be obtained. You should have colder air and less run time. You should also see a 25% to 30% reduction in energy use, cutting power bills, some drastically. Why the United States continues to teach, study, and use the obsolete refrigerants is a mystery to the rest of the world. We all know that synthetic refrigerants have no future in modern technology of cooling and refrigeration.

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Refrigerant Overview

CFC Refrigerants (Chlorofluorocarbons): CFCs contain chlorine, fluorine, and carbon and are considered the most damaging to the environment because their molecules are not destroyed as they reach the stratosphere. They have a very long life when released into the atmoshpere because of their stable chemical structure. Due to their environmental impact, they were phased out of manufacturing at the end of 1995.

Examples:

  • R11 Used for many centrifugal chillers in office buildings and as a parts cleaner
  • R12 Used for automotive air conditioning, residential and light commercial refrigeration, and for some centrifugal chillers in office buildings
  • R113 Used for smaller commercial chillers and as a cleaning solvent
  • R114 Used in some household refrigerators and in centrifugal chillers for marine applications
  • R502 Is a blend of 48.8% R22 and 51.2% R115 - used for low-temperature refrigeration systems

HCFC Refrigerants (Hydrochlorofluorocarbons): HCFCs contain hydrogen, a small amount of chlorine, fluorine, and carbon. The hydrogen in their formula makes them less stable than CFCs. HCFCs thus have a lower potential for ozone depletion as they breakdown in the atmosphere releasing the chlorine before it reaches the ozone layer. HCFCs also have global warming potential. Due to their environmental impact these products are scheduled to be phased out in the coming years.

Example:

  • R22 Used extensively in residential and light commercial air conditioning

HFC Refrigerants (Hydrofluorocarbons): HFCs contain hydrogen, fluorine, and carbon atoms. While they will not deplete the ozone layer they do have global warming potential. For this reason, many nations worldwide are planning their elimination. HFCs generally are not compatible with the natural mineral oils used with the CFCs which they replaced. This has greatly complicated converting R12 systems to the HFC R134a.

Example:

  • R134a Replacement for CFC R12

HC Refrigerants (Hydrocarbons): HCs are natural organic compounds. HC refrigerants have no fluorine or chlorine in their molecule, thus they have no ozone depletion potential and a very low global warming potential as compared to other refrigerants.

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Thermodynamic Properties

Hc12a/134+® and HC22a/502a® are zeotropic blends of natural organic hydrocarbon refrigerants. This patented formula gives HC12a/134+ ® and Hc22a/502a® the optimum thermodynamic properties while providing the highest possible health and safety.

HC12a/134+® and Hc22a/502a® are considerably different molecularly than traditional refrigerants. A molecule of HC12a/134+® is much larger than a molecule of R134a or R12 but weighs only half as much. This larger HC molecule can be compared to a kernel of popped corn, light and fluffy, while the traditional refrigerant molecule can be compared to a corn kernel, small and dense. This large fluffy molecule absorbs, conducts, and releases heat better than the small dense molecule. The large fluffy HC molecule can be compressed much easier than the small dense molecules of traditional refrigerants.

Based upon these molecular advantages, HC refrigerants are more efficient than traditonal refrigerants and require considerably lower high side pressures than R134a for example. Lower operating pressures translate into longer compressor life and fewer leaks. Additionally, electric powered air condition or refrigeration systems converted from traditional refrigerants to HC products commonly experience compressor related energy reductions of 15-50% with equal or improved cooling.

Because HC12a/134+® and HC22a/502a® molecules are larger and lighter, a full charge of HC is achieved at approximately half the weight required by traditional refrigerants. HC12a/134+® is 0.43 times the weight of CFC R12 and 0.5 times the weight of R134a. HC22a/502a® is 0.5 times the weight of HCFC R22 or R502. For example, if a system requires 32 oz. of R134a, the same system would be fully charged with HC refrigerants at approximately 16 oz.

HC12a/134+® and Hc22a/502a® are zeotropic blends and thus have many temperatures as they evaporate and condense at a given pressure. This is called temperature glide. Refrigerants like R12, R134a, and R22 evaporate and condense at one temperature for a given pressure basically dumping their heat in a small area of the condenser. The glide of HC refrigerants reduces hot spots and releases heat more evenly across the condenser while absorbing heat more uniformly across the evaporator. This characteristic makes better use of system components and provides more efficient operation in the hottest environments.

Hc12a/134+® has a normal boiling point of -33.9° C (-29° F). HC22a/502a® has a normal boiling point of -40° C (-40° F).

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Toxicity

Unlike many traditional refrigerants, HC12a/134+® and HC22a/502a® are non-toxic. Additionally there are no toxic by-products generated from thermal decomposition (exposure to heat) in the presence of oxygen.

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Flammability

Recognition is growing that all refrigerants containing hydrogen, including the currently popular HCFCs and HFCs, are potentially combustible under some conditions. HC12a/134+® and HC22a/502a® are hydrocarbon refrigerants and are flammable under certain circumstances. For example, Dupont's documentation for R134a (HFC) indicates an auto ignition temperature at 0 (zero) PSIG of 1418° F while Simtars tested the ignition temperature at 0 (zero) PSIG for HC12a/134+® and HC22a/502a® to be 1627° F; two hundred degrees higher than 134a. Additionally, at 5 PSIG R134a has an ignition temperature of only 370° F while Hc12a/134+® and Hc22a/502a® remain at 1627° F. The truth is HC12a/134+® and Hc22a/502a® actually have lower flammability risks in many cases than products like R134a, which represents the industry standard.

HC12a/134+® and HC22a/502a® are flammable at limited air to gas ratios. HC12a/134+® and Hc22a/502a® have a lower flammability limit of 1.8% gas to air and an upper limit of 8.5% gas to air. In other words, concentrations of HC lower than 1.8% gas to air are too lean to burn and concentrations higher than 8.5% gas to air are too rich to burn. While HC12a/134+® and HC22a/502a® are flammable, the risk of ignition has been shown to be extremely low. HC12a/134+® and HC22a/502a® have been engineered to pose the lowest possible flammability hazard and are safer than hydrocarbon products used routinely in other parts of the world. As of this date (May 2002) there have been no documented incidents of property damage or human injury resulting from HC12a/134+® or Hc22a/502a®.

As an added protection against leaks, a strong odor has been added to HC12a/134+® and Hc22a/502a® so any concentrated leak can be quickly indentified.

Auto Ignition Temp
Refrigerant LFL % UFL % C F
Propylene R1270 2.5 455 851
Iso-butane R600a 1.8 8.5 460 860
CARE30 1.95 9.1 460 860
CARE50 2.2 460 860
Propane R290 2.2 10.2 470 878
Ethane R170 3.0 515 959
HFC R152a 5.1 17.1
HFC R134a 770 1418
HC12a/134+ 1.8 8.9 877 1628

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Environmental Effect

The components of Hc12a/134+® and HC22a/502a® occur naturally. They pose no danger to the ozone layer and are negligible contributors to global warming. Once in the atmosphere, HC refrigerants rapidly breakdown to carbon dioxide and water. While carbon dioxide is considered a "green house gas", it is a very weak one. The significance of carbon dioxide as a "green house gas" is due to the very large quantities released through burning fuels for power generation. By comparison, hydrocarbon refrigerant contribution would have virtually no impact on the environment. Additionally, the lower energy requirements of HC charged systems serve to reduce the amount of carbon dioxide required for energy generation.

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Compatability

Systems Materials: Hc12a/134+® and HC22a/502a® are compatable with all materials commonly found in air conditioning systems such as aluminum, zinc, copper, magnesium, steel, etc.

Lubricating Oils: HC12a/134+® and HC22a/502a® are essentially oils and serve to lubricate the compressor and other moving parts. HC products have low to zero dipole movement so their liquids are non-polar. This means HC12a/134+® and Hc22a/502a® are miscible (mix satisfactorily) with all refrigerant lubricating oils including mineral oil, Alkylbenzene oil, Ester oil, and PAG oil. For this reason, converting systems from traditional refrigerants to HC12a/134+® or HC22a/502a® requires no expensive oil change or flushing.

Hoses: Due to their lower pressures and larger molecules, HC12a/134+® and HC22a/502a® do not require plastic lined barrier hose. Standard rubber air condition hoses are sufficient.

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Contamination

Hc12a/134+® and HC22a/502a® are stable natural oils and unlike traditional refrigerants are not adversely affected by moisture and/or oxygen contamination. HC12a/134+® and HC22a/502a® are compatible with all air conditioning lubricating oils. It should be remembered that synthetic lubricating oils such as Ester and PAG are highly hydroscopic, rapidly absorbing moisture from the atmosphere. Synthetic oils contaminated by moisture can turn caustic inside the system, resulting in compressor damage or other failures. HC refrigerants do not contribute to the damage but act to counter the caustic action of contaminated synthetic oil. When possible it is recommended to use natural mineral lubricating oils such as R12 oil with HC refrigerants. Natural mineral oil is not adversely affected by moisture or oxygen. Contamination should not be a concern when a system contains natural mineral lubricating oil and HC12a/134+® or HC22a/502a®.

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Handling and Detection

Handling: All refrigerants are dangerous and should be handled and stored with care. The main safety concerns with Hc12a/134+® and HC22a/502a® are flammability and asphyxiation. Large quantities of refrigerant should be stored in a well-ventilated area away from open flames. If leaks should occur, HC12a/134+® and HC22a/502a® are heavier than air and will settle in the lowest levels of unventilated areas. A stenching agent has been added to the refrigerant to quickly alert technicians to presence of HC gas. If gas buildup is suspected the area should be ventilated and all open flames should be extinguished.

Detection: Open flame leak detectors are not recommended with hydrocarbon products. Most sniffer type leak detectors work well with hydrocarbons. In addition, special detection equipment is made for use with hydrocarbon products.

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Abundance and Ease of Manufacturing

HC12a/134+® and HC22a/502a® are created from natural organic by-products of the petroleum industry. The raw materials required for production of these products are therefore in abundant supply. As HC12a/134+® and HC22a/502a® are not products of molecular alteration, the manufacturing process is very simple and environmentally friendly as compared to that of synthetic refrigerants.

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Why Do Compressors Fail?

An Autopsy of a Dead Compressor

"Knowledge of the problem is key to the solution!" - Sun Tzu

At Hydro Cool, Inc. we autopsy failed A/C compressors to determine the reason for their premature demise. Our research has identified three primary reasons for compressor failures - high pressure, contaminated oil, and lack of oil.

High Pressure: R12 systems experienced pressures of 250 psi, while R134a systems run at 300 - 350 psi, placing much more stress on compressors. In the last twenty years most compressor manufacturers have switched to nylon and other synthetic fiber piston rings. While these rings tend to seal better and wear less, they also stretch under extreme pressure. High pressures push the rings down on the skirt of the piston where they are sheared into small shreds. These shreds accumulate in the orifice tube or in the condenser resulting in blockages, higher pressure, and ultimately compressor failure.

Contaminated Oil: The introduction of R134a required the use of new synthetic oils such as PAG and Ester oils. These oils are being mixed without consideration of the consequences. Additionally, synthetic oils are frequently combined with mineral oil when systems are "converted" to R134a. Sythetic oils have been described as "acid with the moisture removed". These oils are very hydroscopic by nature as they quickly absorb moisture when exposed to the atmosphere. Contaminated synthetic oil when mixed with R134a becomes a powerful solvent and will actually dissolve rubber and synthetic compressor rings resulting in compressor failures.

For an example of how oils mix, conduct the following experiment:
Take two plastic soda bottles. Pour 2 ounces of PAG oil in the first and 2 ounces of Ester oil in the second. Mix 2 ounces of mineral oil into each bottle. Watch them start to gel. These oils are now contaminated and will not lubricate a compressor properly. This happens in air condition shops daily.

For a second experiment:
Take three plastic soda bottles with lids. Pour 2 ounces of PAG oil in the first, 2 ounces of Ester oil in the second, and 2 ounces of mineral oil in the third. Add 2 ounces of water to each bottle and mix well. The PAG solution washes off the side of the bottle leaving no lubricating residue, the Ester solution performs slightly better. Only the mineral oil continues to lubricate even when contaminated with moisture.

Insufficient Oil: Proper lubrication is essential for extended compressor life. Our research has concluded factory recommended oil amounts are insufficient to achieve maximum compressor life as oil is dispersed throughout the system robbing the compressor of the oil needed for proper lubrication. Lack of sufficient oil galls pistons and blocks, the crankshaft starts to wear causing metal dust to spread throughout the system. This dust results in blockages, high pressure, and compressor failure.

The Solution to Premature Compressor Failure Syndrome

Over nine years of research and experimentation has determined the best combination of oil and refrigerant to restore systems damaged by contamination. If the compressor is replaced we recommend the dryer (accumulator) and the orifice also be replaced. If the system has an expansion valve it should be removed and cleaned.

Flushing: Prior to replacing the above components, the evaporator, condenser and A/C lines should all be flushed. We recommend using a good air conditioner flush. Some flushes are worse than the contamination. We recommend "Air Condition Flush" by Air Repair. It is non-flammable, evaporates quickly, and removes oil and contaminates. We spray in the flush and then blow through the system with compressed air. One can will usually do two or more systems.

In extreme cases we have developed a process to flush with strong detergent and water. We do not recommend the procedure unless you have first contacted us to discuss the details. While every effort is made to remove all moisture from the system, the oil and refrigerant we use is not adversely affected by trace amounts of moisture.

Oil: Lack of oil is one of the primary reasons for compressor failure. After the system is flushed and dry and the above components have been replaced, 14-16 ounces of mineral oil should be added prior to charging the system. Mineral oil is much superior to PAG or Ester oil because it is not adversely affected by moisture. Our experience has concluded that 14-16 ounces of oil results in a well lubricated system which cools well. The four to six ounces recommended by most manufacturers is soon spread throughout the system and as a result the compressor on most new vehicles lasts only long enough for the warranty to expire. By adding 14-16 ounces of oil, the compressor is well lubricated and will never fail for lack of lubrication. By using only mineral oil your compressor will never fail as a result of contaminated oil.

Refrigerant: Our experience has concluded that HC12a/134+® (pure hydrocarbon refrigerant) is the finest refrigerant available. It functions at a much lower pressure than R134a and generally lower pressures than R12. It is also not contaminated by atmospheric moisture. Low pressure and resistance to contamination eliminate the third major reason for compressor failure. HC12a/134+® is an oil and unlike other refrigerants actually serves to lubricate your system. In addition, due to its easier compression, HC12a/134+® does not pull your engine down like other refrigerants.

A system which has been properly flushed, fitted with a new compressor, dryer, and orifice tube, filled with 14-16 ounces of mineral oil, and properly charged with HC12a/134+® should provide many years of trouble free comfort. Such a system is contaminate resistant, well lubricated, and runs at a low pressure thus eliminating all three of the primary causes of premature death in the automotive compressor.

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Composition of Refrigerant Blends

Ozone Protection Hotline (800) 296- 1996

The following tables show the percentage composition of refrigeration blends found acceptable, acceptable subject to narrowed use limits, or acceptable subject to use conditions. The specific determinations that apply to these blends are listed by end-use. In addition, a chronological list of SNAP updates is available from the hotline. If your browser is unable to display tables, please call the hotline for a free paper copy of these tables.

Note: SNAP Notices and Final Rules published in the Federal Register take precedence over all information on the web site.

Percentage Composition of Substitutes for CFC-12
Trade Name ASHRAE Number HCFCs HFCs HCs
22 124 142b 134a 152a 227ea butane (R-600) iso-butane (R-600a)
MP-39 401A 53% 34%

13%


MP-66 401B 61% 28%

11%


MP-52 401C 33% 52%

15%


GHG 406A 55%
41%



4%
FX-56 409A 60% 25% 15%




FRIGC FR-12

39%
59%

2%
Free Zone (2% is a lubricant)


19% 79%



GHG-HP
65%
31%



4%
Hot Shot 414B 50% 39% 9.5%



1.5%
GHG-X4 414A 51% 28.5% 16.5%



4%
Freeze 12


20% 80%



GHG-X5
41%
15%

40%
4%


Substitutes for R-502
Trade Name ASHRAE Number HCFC-22 HFCs HCs
32 125 134a 143a 152a propane propylene
HP-80 402A 38%
60%


2%
HP-81 402B 60%
38%


2%
HP-62, FX-70 404A

44% 4% 52%


KLEA 407A 407A
20% 40% 40%



KLEA 407B 407B
10% 70% 20%



FX-10 408A 46%
7%
47%


R-411A 411A 87.5%



11%
1.5%
R-411B 411B 94%



3%
3%
G2018C
95.5%



1.5%
3%
AZ-50 507

50%
50%




Substitutes for HCFC-22
Trade Name ASHRAE Number HFC-32 HFC-125 HFC-134a
KLEA 407C, AC9000 407C 23% 25% 52%
AZ-20, Puron, Suva 9100 410A 50% 50%
AC9100 410B 45% 55%



Substitutes for CFC-113, R-13B1, and R-503
Trade Name ASHRAE Number HCFC-22 HFC-23 HFC-152a Propane PFC-116 (perfluoroethane) PFC-218 (perfluoropropane)
R-403B 403B 56%

5%
39%
KLEA 5R3 508A
39%

61%
Suva 95 508B
46%

54%
NARM-502
90% 5% 5%


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